Criteria for Using Approximative Relations for the Calculation of Simple Protolytic Equilibria. Weak Bases and Hydrolyzed Salts

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  • P. Tomčík Institute of Analytical Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology, Bratislava, Slovak Republic
  • V. Klbiková Institute of Analytical Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology, Bratislava, Slovak Republic
  • D. Bustin Institute of Analytical Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology, Bratislava, Slovak Republic

Abstrakt

The criteria were derived for simple protolytic equilibria of weak bases and hydrolyzed salts in aqueous solutions. The approximative formulae (simpler equations) can be used if the analytical concentration of a protolyte is higher than the limiting (critical) concentration calculated from the derived criterial equation. The concentration ranges in which it is appropriate to use various mathematical types of equations or the simplest formula are calculated and discussed.

Stahování

Publikováno

15.07.2009

Jak citovat

Tomčík, P., Klbiková, V., & Bustin, D. (2009). Criteria for Using Approximative Relations for the Calculation of Simple Protolytic Equilibria. Weak Bases and Hydrolyzed Salts. Chemické Listy, 103(6). Získáno z http://chemicke-listy.cz/ojs3/index.php/chemicke-listy/article/view/1530

Číslo

Vol 103 No 6 (2009)

Sekce

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