Molecular Recognition with Novel Chromatographic Phases Based on Combination of Porphyrins and Expanded Porphyrins with Chiral Binaphthyl Derivatives: Application for the Separation of Biologically Important Substrates

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  • I. Kavenova * * Department of Analytical Chemistry,** Department of Organic Chemistry, Institute of Chemical Technology, Prague; *** Department of Organic Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas, USA
  • R. Holakovsky ** * Department of Analytical Chemistry,** Department of Organic Chemistry, Institute of Chemical Technology, Prague; *** Department of Organic Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas, USA
  • M. Hovorka ** * Department of Analytical Chemistry,** Department of Organic Chemistry, Institute of Chemical Technology, Prague; *** Department of Organic Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas, USA
  • V. Kriz * * Department of Analytical Chemistry,** Department of Organic Chemistry, Institute of Chemical Technology, Prague; *** Department of Organic Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas, USA
  • P. Anzenbacher Jr. * * Department of Analytical Chemistry,** Department of Organic Chemistry, Institute of Chemical Technology, Prague; *** Department of Organic Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas, USA
  • P. Matejka * * Department of Analytical Chemistry,** Department of Organic Chemistry, Institute of Chemical Technology, Prague; *** Department of Organic Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas, USA
  • V. Kral * * Department of Analytical Chemistry,** Department of Organic Chemistry, Institute of Chemical Technology, Prague; *** Department of Organic Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas, USA
  • J. W. Genge *** * Department of Analytical Chemistry,** Department of Organic Chemistry, Institute of Chemical Technology, Prague; *** Department of Organic Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas, USA
  • J. L. Sessler *** * Department of Analytical Chemistry,** Department of Organic Chemistry, Institute of Chemical Technology, Prague; *** Department of Organic Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas, USA

Abstrakt

A novel possibility for the chiral separation mode based on multiple recognition by mixed macrocycle-binaphthyl ligands on derivatized aminopropylsilica gel HPLC sorbents is presented. These novel chromatographic sorbents showed a great potential for aminoacid and saccharide separations.

Stahování

Publikováno

15.03.1998

Jak citovat

*, I. K., **, R. H., **, M. H., *, V. K., *, P. A. J., *, P. M., *, V. K., ***, J. W. G., & ***, J. L. S. (1998). Molecular Recognition with Novel Chromatographic Phases Based on Combination of Porphyrins and Expanded Porphyrins with Chiral Binaphthyl Derivatives: Application for the Separation of Biologically Important Substrates. Chemické Listy, 92(2). Získáno z http://chemicke-listy.cz/ojs3/index.php/chemicke-listy/article/view/2731

Číslo

Vol 92 No 2 (1998)

Sekce

Články