Vliv aktivující báze na průběh transfer hydrogenace acetofenonu s rutheniovým katalyzátorem

  • J. Pecháček Ústav organické technologie, Vysoká škola chemicko-technologická v Praze, Praha
  • M. Kuzma Ústav organické technologie, Vysoká škola chemicko-technologická v Praze, Praha
  • P. Kačer Ústav organické technologie, Vysoká škola chemicko-technologická v Praze, Praha
Klíčová slova: transfer hydrogenace, vliv báze

Abstrakt

In the presented work, a highly active catalyst for the transfer hydrogenation of ketones was prepared. By reaction testing with acetophenone as a model substrate, the influence of the catalytic base on the activity of the catalyst was assessed. Potassium tert-butoxide was ultimately found to be the most suitable base, providing highest activity of the catalyst. Subsequently it was discovered that the base plays an important role in the activation of the substrate.

Publikované
2016-10-15
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