Natural Materials Rich in Montmorillonite: Simultaneous Measurement of Expansion and Sorption

Page: 246

R. Hanusa, I. Kolaříkováa, L. Brabecb*, M. Kočiříkb, R. Přikryla, E. Jelíneka, and A. Zikánováb

a Institute of Geochemistry, Mineralogy and Mineral Resources, Faculty of Science, Charles University in Prague, Prague, b J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic


A combined flow technique for study of sorption properties of clay materials has been developed. First, water desorption is recorded and, subsequently, simultaneous measurements of water adsorption and of clay-bed expansion are performed. The technique is expected to become a powerful tool for determination of the generic type of clay materials and to provide information on the content of smectic components in the clay. From adsorption-desorption runs, data on equilibrium sorption of water in clay and on the sorption kinetics can be obtained.


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