Analysis of Blast Furnace Slags by Laser-Ablation Optical Emission Spectrometry with Inductively Coupled Plasma

Page: 697

M. Pištěkováa, V. Otrubab,d, and V. Kanickýc,d

a Institute of Chemistry, University of Technology, Brno, b Plasmachemical Laboratory, Department of Physical Electronics, Masaryk University, Brno, c Research Centre for Environmental Chemistry and Ecotoxicology, Laboratory of Atomic Spectrochemistry, Department of Chemistry, Masaryk University, Brno, d Laboratory of Atomic Spectrochemistry, Department of Chemistry, Masaryk University, Brno

 

Laser ablation (LA) has been used as a direct solid-sample introduction technique in analysis of blast-furnace slags by inductively coupled plasma optical emission spectrometry (ICP-OES). Pressed pellets containing slag and a binder, powdered Ag or a LiBO2 - Ag mixture and an internal standard are used. The LiBO2 mixture was found optimal. A linear calibration curve was obtained up to specified contents of metal oxides. As follows from comparison of different methods of analysis of blast-furnace slags, using reference materials and real samples, the LA ICP-OES is a suitable method for the purpose.

 

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