Miniaturization of Flow-Through Electrolytic Cells for Electrochemical Generation of Volatile Compound in AAS

Page: 200

J. Hraníček, V. Červený, and P. Rychlovský

Department of Analytical Chemistry, Faculty of Natural Science, Charles University, Prague


Two types of miniaturized flow-through electrolytic cells, without exchange membranes and with minimal inner volume, for electrochemical hydride generation in AAS were designed. For one of these cells, a higher sensitivity and better limit of detection in Se determination by hydride-generation AAS and electrochemical generation of Se hydride were attained than in the classical thin-layer flow-through cell.


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